155157-75-8Relevant academic research and scientific papers
An efficient synthesis of the dolabellanes
Williams,Coleman,Nevill,Robinson
, p. 7895 - 7898 (1993)
Eleven-membered carbocycles have been prepared by the intramolecular condensations of α-sulfonyl carbanions with α,β-unsaturated aldehydes. Desulfonylation provides an efficient stereocontrolled synthesis of allylic alcohols featuring the [9.3.0] cyclotetradecane skeleton which characterized the dolabellane diterpenes.
Strategies for the synthesis of fusicoccanes by nazarov reactions of dolabelladienones: Total synthesis of (+)-fusicoauritone
Williams, David R.,Robinson, Leslie A.,Nevill, C. Richard,Reddy, Jayachandra P.
, p. 915 - 918 (2008/02/01)
Attaining closure: A synthetic pathway leading to (+)-fusicoauritone (1) is highlighted by the use of a Julia condensation for preparation of an eleven-membered-dolabelladienone precursor for subsequent Nazarov cyclization to yield the 5-8-5 tricyclic dit
