155191-80-3Relevant academic research and scientific papers
Diastereoselective Total Syntheses of (+/-)-Triptoquinone B and C
Shishido, Kozo,Goto, Kiyoto,Tsuda, Asae,Takaishi, Yoshihisa,Shibuya, Masayuki
, p. 793 - 794 (2007/10/02)
The first and efficient total syntheses of (+/-)-triptoquinone B 1 and C 2 have been achieved from the allyl ether 3; the key steps are the construction of the four contiguous stereogenic centers present in 2 by the Mn(III) mediated oxidative free radical cyclisation followed by metal hydride reduction.
