155231-61-1Relevant academic research and scientific papers
Molecular tools for the self-assembly of bisporphyrin photodyads: A comprehensive physicochemical and photophysical study
Brandel, Jeremy,Trabolsi, Ali,Traboulsi, Hassan,Melin, Frederic,Koepf, Matthieu,Wytko, Jennifer A.,Elhabiri, Mourad,Weiss, Jean,Albrecht-Gary, Anne-Marie
, p. 3743 - 3754 (2009/09/26)
Accessible and hindered phenanthroline-strapped Zn(II) porphyrin receptors exhibited suitable topography tailored to strongly and selectively bind N 1-unsubstituted imidazoles and imidazoles appended to free-base porphyrins. Distal binding was
Recognition of imidazoles by strapped zinc(II) porphyrin receptors: Insight into the induced-fit mechanism
Brandel, Jeremy,Trabolsi, Ali,Melin, Frederic,Elhabiri, Mourad,Weiss, Jean,Albrecht-Gary, Anne-Marie
, p. 9534 - 9536 (2008/10/09)
Imidazole-porphyrin coordination has become an important tool in the design of self-assembled materials. A combination of spectrophotometric and stopped-flow techniques has been used to gain insight into the control of imidazole binding in the distal pocket of phenanthroline-strapped porphyrins. The binding studies of a variety of imidazole substrates in combination with both hindered and accessible receptors have permitted the determination of the thermodynamic and kinetic parameters associated with the imidazole binding.
