155312-77-9

Basic information

• Product Name: 3-tert-butyldiphenylsilyloxymethyl-3-(4-oxopentyl)-1,4-cyclohexadiene
• Synonyms: 3-tert-butyldiphenylsilyloxymethyl-3-(4-oxopentyl)-1,4-cyclohexadiene
• CAS NO: 155312-77-9
• Molecular Weight: 432.678
• Mol File: 155312-77-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-tert-butyldiphenylsilyloxymethyl-3-(4-oxopentyl)-1,4-cyclohexadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-tert-butyldiphenylsilyloxymethyl-3-(4-oxopentyl)-1,4-cyclohexadiene(155312-77-9)
• EPA Substance Registry System: 3-tert-butyldiphenylsilyloxymethyl-3-(4-oxopentyl)-1,4-cyclohexadiene(155312-77-9)

Safety Data

• Hazardous Substances Data: 155312-77-9(Hazardous Substances Data)

Upstream product

• 155312-75-7 1-[3-(2-Methyl-[1,3]dioxolan-2-yl)-propyl]-cyclohexa-2,5-dienecarboxylic acid methyl ester 
• 155312-76-8 {1-[3-(2-Methyl-[1,3]dioxolan-2-yl)-propyl]-cyclohexa-2,5-dienyl}-methanol 
• 30889-20-4 methyl cyclohexa-2,5-diene-1-carboxylate 
• 3695-28-1 5-iodo-2-pentanone ethylene ketal 
• 58479-61-1 tert-butylchlorodiphenylsilane 

Downstream Products

• 155312-78-0 3-tert-butyldiphenylsilyloxymethyl-3-(4-trifluoromethanesulfonyloxy-4-pentenyl)-1,4-cyclohexadiene 
• 155312-79-1 4-tert-butyldiphenylsilyloxymethyl-4-(4-trifluoromethanesulfonyloxy-4-pentenyl)-2,5-cyclohexadien-1-one 

Relevant articles and documents

Asymmetric Heck reaction: Catalytic asymmetric syntheses of bicyclic enones, dienones and the key intermediate for vernolepin

Bicyclic enone 23a, a functionalized decalin derivative, has been synthesized in up to 86% ee by an asymmetric Heck reaction starting with bisallylic alcohol 24. Enone 23a has been converted to 19, a key intermediate in the synthesis of vernolepin (14). F