155342-92-0Relevant academic research and scientific papers
Disulfur-bridged Complexes of Molybdenum. Crystal Structure of the Dimolybdenum(IV) Complex 2(μ-S2)(μ-C4H8S)> and of the Mo(IV)Mo(V) Complex
Hughes, David L.,Lane, Janette D.,Richards, Raymond L.,Shortman, Caroline
, p. 621 - 626 (1994)
Treatment of with S2Cl2 gave a very dark green material of empirical formula Mo2S2Cl6*CH2Cl2 1 which, on reaction with L, gave green 2(μ-S2)(μ-L)> (L = C4H8S 2a, PhCH2SMe 2b or C4H8O 2c), and with SMe2 gave the novel, brown, unsymmetrical, mixed-oxidation-state complex 3.The structures of 2a and 3 have been established by X-ray crystallography.Compounds 2a-2c are diamagnetic and NMR data have been obtained, whereas 3 is paramagnetic and shows, in a CH2Cl2 glass at 40 K, a broad, roughly axial EPR resonance with gmax at 1.94.
