Disulfur-bridged Complexes of Molybdenum. Crystal Structure of the Dimolybdenum(IV) Complex 2(μ-S2)(μ-C4H8S)> and of the Mo(IV)Mo(V) Complex

DOI: 10.1039/DT9940000621

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 621 - 626 (1994)

Update date:2022-08-16

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Authors:

Hughes, David L.

Lane, Janette D.

Richards, Raymond L.

Shortman, Caroline

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Article abstract of DOI:10.1039/DT9940000621

Treatment of with S2Cl2 gave a very dark green material of empirical formula Mo2S2Cl6*CH2Cl2 1 which, on reaction with L, gave green <2(μ-S2)(μ-L)> (L = C4H8S 2a, PhCH2SMe 2b or C4H8O 2c), and with SMe2 gave the novel, brown, unsymmetrical, mixed-oxidation-state complex <(Me2S)2Cl2Mo(μ-S2)(μ-S)MoCl3(SMe2)> 3.The structures of 2a and 3 have been established by X-ray crystallography.Compounds 2a-2c are diamagnetic and NMR data have been obtained, whereas 3 is paramagnetic and shows, in a CH2Cl2 glass at 40 K, a broad, roughly axial EPR resonance with g_max at 1.94.

Full text of DOI:10.1039/DT9940000621

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