155366-47-5Relevant academic research and scientific papers
Synthesis of (-)-Muricatacin and -(5R,6S)-6-acetoxy-5-hexadecanolide, the Mosquito oviposition attractant pheromone, from D-isoascorbic acid
Gravier-Pelletier, Christine,Saniere, Michele,Charvet, Isabelle,Le Merrer, Yves,Depezay, Jean-Claude
, p. 115 - 118 (1994)
From D-isoascorbic acid, a general approach to enantiomerically pure hydroxy γ-butyro and δ-valero lactones, (-)-Muricatacin and (-)-(5R,6S)-6-acetoxy-5-hexadecanolide, via a four carbon atoms bisepoxide equivalent, is reported.
Enantioselective synthesis of (-)-(5R,6S)-6-acetoxyhexadecan-5-olide via tandem α-aminooxylation-Henry reaction
Pandey, Rachana,Garg, Yuvraj,Prakash, Ranjana,Pandey, Satyendra Kumar
, p. 20 - 27 (2018)
novel enantioselective synthetic approach of (-)-(5R,6S)-6-acetoxyhexadecan-5-olide, an oviposition attractant pheromone of the mosquito Culex pipiens fatigans is presented, starting from n-dodecanal. The synthesis features tandem α-aminooxylation-Henry a
Enantiopure hydroxylactones from L-ascorbic and D-isoascorbic acids. Part II. Synthesis of (-)-(5R,6S)-6-acetoxy-5-hexadecanolide and its diastereomers
Gravier-Pelletier,Le Merrer,Depezay
, p. 1663 - 1674 (2007/10/02)
Strategies to enantiopure 6-hydroxy-δ-valerolactones, through bis-epoxide formal equivalents issued from L-ascorbic and D-isoascorbic acids, are studied. The approaches notably involve Mitsunobu reaction on diols or triols and opening of the resulting epoxides.
