155366-79-3Relevant academic research and scientific papers
1,3-asymmetric induction in electrophilic addition onto homoallylsilanes. An approach towards the total synthesis of (+/-)-kumausyne
Audrey, Olivier,Glanzmann, Cecile,Landais, Yannick,Parra-Rapado, Liliana
, p. 2835 - 2854 (1997)
Electrophilic 5-exo-trig cyclizations of homoallylsilanes have been carried out leading to 2,4- and 2,4,5-substituted tetrahydrofurans with good yields and diastereoselectivities. With disubstituted homoallylsilanes, tetrahydrofurans having acyclic chiral
Highly Stereoselective Access to 2,4- and 2,4,5-Substituted Tetrahydrofurans from α-Silylacetic Esters. A Study of Homoallylic Stereocontrol.
Andrey, Olivier,Landais, Yannick
, p. 8435 - 8438 (2007/10/02)
Cis-2,4- and cis-cis-2,4,5-substituted tetrahydrofurans have been prepared stereoselectively using electrophile-mediated cyclization of β-hydroxyhomoallylsilanes, readily available from α-silylacetic esters.
