1,3-asymmetric induction in electrophilic addition onto homoallylsilanes. An approach towards the total synthesis of (+/-)-kumausyne

DOI: 10.1016/S0040-4020(97)00003-3

Source and publish data:

Tetrahedron p. 2835 - 2854 (1997)

Update date:2022-07-29

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Authors:

Audrey, Olivier

Glanzmann, Cecile

Landais, Yannick

Parra-Rapado, Liliana

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Article abstract of DOI:10.1016/S0040-4020(97)00003-3

Electrophilic 5-exo-trig cyclizations of homoallylsilanes have been carried out leading to 2,4- and 2,4,5-substituted tetrahydrofurans with good yields and diastereoselectivities. With disubstituted homoallylsilanes, tetrahydrofurans having acyclic chiral

Full text of DOI:10.1016/S0040-4020(97)00003-3

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