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3-Octanol, 2-[(R)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (2R,3R)- is a complex organic compound with the molecular formula C16H31SO2Si. It is a chiral molecule, with the (2R,3R) configuration indicating the specific arrangement of atoms in the molecule. 3-Octanol, 2-[(R)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (2R,3R)- features a 3-octanol backbone, which is an eight-carbon alcohol chain, with a trimethylsilyl group attached to the first carbon and a (4-methylphenyl)sulfinyl group attached to the second carbon. The (4-methylphenyl)sulfinyl group is a sulfur-containing functional group derived from a 4-methylphenol, which adds to the molecule's complexity. 3-Octanol, 2-[(R)-(4-methylphenyl)sulfinyl]-1-(trimethylsilyl)-, (2R,3R)- is of interest in organic chemistry and may have applications in the synthesis of pharmaceuticals or other specialty chemicals due to its unique structure and properties.

155394-02-8

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155394-02-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 155394-02-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,5,3,9 and 4 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 155394-02:
(8*1)+(7*5)+(6*5)+(5*3)+(4*9)+(3*4)+(2*0)+(1*2)=138
138 % 10 = 8
So 155394-02-8 is a valid CAS Registry Number.

155394-02-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name (2R,3R)-2-[(R)-(4-methylphenyl)sulfinyl]-1-trimethylsilyloctan-3-ol

1.2 Other means of identification

Product number -
Other names (2R,3R,RS)-2-(p-tolylsulfinyl)-1-(trimethylsilyl)octan-3-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
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More Details:155394-02-8 SDS

155394-02-8Downstream Products

155394-02-8Relevant academic research and scientific papers

Asymmetric reduction of α-(trimethylsilyl)methyl-β-ketosulfoxide with DIBAL under basic conditions

Nakamura, Shuichi,Nakayama, Jun-ichi,Toru, Takeshi

, p. 5766 - 5768 (2007/10/03)

The reaction of the α-carbanion of p-tolyl 2-(trimethylsilyl)ethyl sulfoxide with esters followed by reduction with DIBAL gave α-(trimethylsilyl)methyl-β-hydroxysulfoxides with high stereoselectivity. The stereoselective reaction was demonstrated to proceed through a dynamic kinetic resolution pathway via a six-membered cyclic transition state involving Si-O interaction. These reactions provide a convenient route for the synthesis of optically pure allylic alcohols.

Vinyl Anion Equivalent V. Asymmetric Synthesis of Allylic Alcohols Using Chiral 2-(Trialkylsilyl)ethyl Sulfoxides

Kusuda, Shinya,Ueno, Yoshio,Toru, Takeshi

, p. 1045 - 1062 (2007/10/02)

Both enantiomers of optically pure secondary allylic alcohols can be conveniently prepared by the diastereoselective reaction of the α-sulfinyl carbanion of p-tolyl 2-(trialkylsilyl)ethyl sulfoxides or tert-butyl 2-(trimethylsilyl)ethyl sulfoxide with aldehydes followed by either fluoride-induced desilylsulfinylation or thermal elimination of the sulfinyl group.

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