153123-09-2

Basic information

• Product Name: Silane, trimethyl[2-[(R)-(4-methylphenyl)sulfinyl]ethyl]-
• CAS NO: 153123-09-2
• Molecular Formula: C12H20OSSi
• Molecular Weight: 240.442
• Mol File: 153123-09-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[2-[(R)-(4-methylphenyl)sulfinyl]ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[2-[(R)-(4-methylphenyl)sulfinyl]ethyl]-(153123-09-2)
• EPA Substance Registry System: Silane, trimethyl[2-[(R)-(4-methylphenyl)sulfinyl]ethyl]-(153123-09-2)

Safety Data

• Hazardous Substances Data: 153123-09-2(Hazardous Substances Data)

Upstream product

• 163524-41-2 1-[(4-methylphenyl)sulfanyl]-2-(trimethylsilyl)ethane 
• 4206-67-1 iodo(trimethylsilyl)methane 
• 1519-39-7 (R)-methyl p-tolyl sulfoxide 

Downstream Products

• 191422-45-4 (1R,3R)-2,2-Dimethyl-3-[(R)-1-((R)-toluene-4-sulfinyl)-2-trimethylsilanyl-ethyl]-cyclopropanecarboxylic acid ethyl ester 
• 191422-42-1 methyl (R_S,4R)-4-(p-tolylsulfinyl)-5-(trimethylsilyl)pentanoate 
• 191422-43-2 methyl (R_S,3S,4R)-3-methyl-4-(p-tolylsulfinyl)-5-trimethylsilylpentanoate 
• 155394-01-7 (1R,2R)-1-phenyl-2-<(R)-p-tolylsulfinyl>-3-(trimethylsilyl)-1-propanol 
• 155486-93-4 (1S,2R)-1-phenyl-2-<(R)-p-tolylsulfinyl>-3-(trimethylsilyl)-1-propanol 
• 264613-49-2 methyl (3R,4R)-3-phenyl-4-[(R)-p-tolylsulfinyl]-5-(trimethylsilyl)pentanoate 
• 264613-73-2 methyl (R_S,2S,3S,4R)-3-phenyl-2-phenylmethyl.4.(p-tolylsulfinyl)-5-(trimethylsilyl)pentanoate 
• 264613-71-0 methyl (R_S,2S,3R,4R)-3-phenyl-2-(2-propenyl)-4-(p-tolylsulfinyl)-5-(trimethylsilyl)pentanoate 

Relevant articles and documents

Asymmetric chemical oxidations of aryl and alkyl 2-(trimethylsilyl)ethyl sulfides

A collection of aryl and alkyl 2-(trimethylsilyl)methyl sulfides have been converted to their respective sulfoxides by four different asymmetric oxidizing agents. The chemical yields range from 44-98% while the enantiomeric excesses range from 0-89%. The

Convenient Preparation of Optically Pure Propargylic Alcohols Using 2-(Trimethylsilyl)vinyl Sulfoxide As A Novel Chiral Synthon

Both enentiomers of optically pure propargylic alcohols are conveniently prepared by the reaction of α-vinyl anion of 2-(trimethylsilyl)vinyl p-tolyl sulfoxide with aldehydes and subsequent either desilylsulfination or thermal elimination of the sulfinyl group.