155397-42-5Relevant academic research and scientific papers
Synthesis of Wieland-Miescher ketone analogues-potential substrates for the carbocyclic frameworks
Rajamannar,Balasubramanian
, p. 279 - 292 (1994)
The synthesis of the hitherto unknown 3, 4, 8, 8a-tetrahydro-8a (2-bromo- 1-cyclo-alkenylmethyl)-1, 6(2H, 7H)-naphthalene-diones are reported.
Intramolecular Competitive Addition of Vinyl Radicals to Keto and Alkenyl Groups in Wieland-Miescher Ketones-Synthesis of Carbocycles and Propellanes
Rajamannar, Thennati,Balasubramanian, Kalpattu Kup.
, p. 25 - 26 (2007/10/02)
Wieland-Miescher ketone analogues are prepared by monoalkylation of cyclohexane-1,3-dione with bromomethylcycloalkenyl bromides followed by annulation with methyl vinyl ketone; they undergo 5-exo-trig competitive intramolecular radical addition to the keto and enone olefins to give angularly fused carbocycles and propellanes, respectively.
