155434-13-2

Basic information

• Product Name: (2R,3S,4S,6S)-2-Allyl-4-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-pyran
• Synonyms: (2R,3S,4S,6S)-2-Allyl-4-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-pyran
• CAS NO: 155434-13-2
• Molecular Weight: 631.015
• Mol File: 155434-13-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2R,3S,4S,6S)-2-Allyl-4-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4S,6S)-2-Allyl-4-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-pyran(155434-13-2)
• EPA Substance Registry System: (2R,3S,4S,6S)-2-Allyl-4-benzyloxy-6-(tert-butyl-diphenyl-silanyloxymethyl)-3-triethylsilanyloxy-tetrahydro-pyran(155434-13-2)

Safety Data

• Hazardous Substances Data: 155434-13-2(Hazardous Substances Data)

Upstream product

• 122821-82-3 2,6-Anhydro-1-O-(tert-butyldiphenylsilyl)-3,7,8,9-tetradeoxy-4,5-O-isopropylidene-D-altro-non-8-enitol 
• 122821-81-2 2,6-Anhydro-1-O-(tert-butyldiphenylsilyl)-3,7,8,9-tetradeoxy-4,5-O-isopropylidene-D-altro-non-8-enitol 
• 100-39-0 benzyl bromide 
• 79271-56-0 triethylsilyl trifluoromethyl sulfonate 
• 122821-83-4 2,6-Anhydro-4-O-benzyl-1-O-(tert-butyldiphenylsilyl)-3,7,8,9-tetradeoxy-D-altro-non-8-enitol 
• 994-30-9 triethylsilyl chloride 

Downstream Products

• 221381-13-1 5-benzyloxy-2-{3-[5-(tert-butyl-dimethyl-silanyloxy)-2-phenyl-[1,3]dioxan-4-yl]-propenyl}-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracene 
• 221381-14-2 C₅₁H₈₄O₉Si₃ 
• 205865-14-1 (2R,4S,5R)-4-((Z)-3-{(2R,4aR,5S,7R,8aR,9aS,10aS)-5-Benzyloxy-7-[3-(tert-butyl-diphenyl-silanyloxy)-propyl]-3,3-bis-ethylsulfanyl-decahydro-1,8,10-trioxa-anthracen-2-yl}-allyl)-2-phenyl-[1,3]dioxan-5-ol 
• 221381-15-3 C₄₉H₈₂O₈Si₃ 
• 221381-16-4 C₄₉H₈₀O₈Si₃ 
• 221381-17-5 C₄₇H₇₆O₇S₂Si₂ 
• 205864-92-2 C₄₇H₇₄O₇S₂Si₂ 
• 221380-99-0 {(2S,3S)-3-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxymethyl)-octahydro-pyrano[3,2-b]pyran-2-ylmethyl]-oxiranyl}-methanol 
• 221380-97-8 (E)-4-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxymethyl)-octahydro-pyrano[3,2-b]pyran-2-yl]-but-2-enoic acid methyl ester 
• 221380-98-9 (E)-4-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxymethyl)-octahydro-pyrano[3,2-b]pyran-2-yl]-but-2-en-1-ol 
• 221381-01-7 (2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxymethyl)-2-((2S,3S)-3-vinyl-oxiranylmethyl)-octahydro-pyrano[3,2-b]pyran 
• 221381-00-6 (2R,3S)-3-[(2R,3S,4aR,6S,8S,8aS)-8-Benzyloxy-3-(tert-butyl-dimethyl-silanyloxy)-6-(tert-butyl-diphenyl-silanyloxymethyl)-octahydro-pyrano[3,2-b]pyran-2-ylmethyl]-oxirane-2-carbaldehyde 

Relevant articles and documents

Total synthesis of brevetoxin A: Part 3: Construction of GHIJ and BCDE ring systems

Successful syntheses of highly complex intermediates 2 (GHIJ ring system) and 3 (BCDE ring system) for the total synthesis of brevetoxin A (1) are described. Several of our methodologies were utilized to achieve this goal: i) hydroxy epoxide cyclizations

Stereocontrolled Synthesis of the Hemibrevetoxin Ring System via an Allylic Tin Method

Stereocontrolled synthesis of the 7,7,6,6-tetracyclic ether skeleton of the hemibrevetoxin skeleton has been accomplished via the intramolecular allylic tin-aldehyde and ketone) condensation.