1554533-30-0Relevant academic research and scientific papers
An unexpected semi-hydrogenation of a ligand in the complexation of 2,7-bispyridinyl-1,8-naphthyridine with Ru3(CO)12
Liao, Bei-Sih,Liu, Yi-Hung,Peng, Shie-Ming,Reddy, K. Rajender,Liu, Shin-Hung,Chou, Pi-Tai,Liu, Shiuh-Tzung
, p. 3557 - 3562 (2014)
Thermal reaction of 2,7-bis(2-pyridinyl)-l,8-naphthyridine (bpnp) with Ru3(CO)12 in the presence of moisture resulted in the formation of a formate-bridged diruthenium complex [(bpnp-H3)Ru 2(μ-HCOO)(CO)4] (1), in which the ligand was partially hydrogenated. Complex 1 was fully characterized by spectroscopic analyses and X-ray single crystal determination. Regarding the partially reduced ligand in 1, it occurs through a water-gas shift type reduction. The bridging formate ligand can be substituted by other carboxylate ligands. Physical and chemical properties of the newly prepared complexes were investigated.
