155485-57-7Relevant academic research and scientific papers
Activation of acrylate-moiety by strain and fluoroalkyl substitution in 4-chloro-3,3,4-trifluoromethoxycarbonyl cyclobutene
Plancquaert, Marie-Aimee,Francois, Philippe,Merenyi, Robert,Viehe, Heinz G.
, p. 7265 - 7268 (1991)
A two step preparation is reported for the title cyclobutene derivative 3 starting from 2-phenylthioacrylate 1 and chlorotrifluoroethylene followed by oxidative elimination. Strain and polarity facilitate reactions with nucleophiles, radicals, dienes and diazoalkanes.
