Tetrahedron Letters p. 7265 - 7268 (1991)
Update date:2022-08-04
Topics:
Plancquaert, Marie-Aimee
Francois, Philippe
Merenyi, Robert
Viehe, Heinz G.
A two step preparation is reported for the title cyclobutene derivative 3 starting from 2-phenylthioacrylate 1 and chlorotrifluoroethylene followed by oxidative elimination. Strain and polarity facilitate reactions with nucleophiles, radicals, dienes and diazoalkanes.
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Doi:10.1039/c4ra05568c
(2014)Doi:10.1021/jo00090a046
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