155488-92-9Relevant academic research and scientific papers
A Formal Synthesis of Aplysiatoxin: Enantioselective Synthesis of Kishi's Aldehyde
Okamura, Hiroaki,Kuroda, Satoru,Ikegami, Satoru,Tomita, Kenji,Sugimoto, Yu-ichi,et al.
, p. 10531 - 10554 (2007/10/02)
This paper describes the enantioselective synthesis of key fragments (12,18,24, and 35) for the synthesis of aplysiatoxin (1a), a potent cancer promoter, and their convergent assembly to Kishi's aldehyde (2).Since 2 has already been transformed into 1a in
Stereoselective Synthesis of erythro-Serricornin, (4R,6R,7S)-, and (4S,6R,7S)-4,6-Dimethyl-7-hydroxynonan-3-one, Stereoisomers of the Sex Pheromone of Cigarette Beetle
Chuman, Tatsuji,Kohno, Masahiro,Kato, Kunio,Noguchi, Masao,Nomi, Hiroko,Mori, Kenji
, p. 2019 - 2024 (2007/10/02)
A stereoselective synthesis of erythro-serricornin was completed starting from L-(+)-tartaric acid.The relative configuration of C(6)-methyl and C(7)-hydroxyl groups in naturally occurring serricornin was threo.
