155494-25-0Relevant academic research and scientific papers
Optical Resolution of 2- and 3-Hydroxyalkyltriphenylphosphonium Salts. Stereoselective Synthesis of Enantiomerically Pure (E)- and (Z)-Homoallylic Alcohols
Okuma, Kentaro,Tanaka, Yuichiro,Ohta, Hiroshi,Matsuyama, Haruo
, p. 2623 - 2632 (1993)
Optically active 2- and 3-hydroxyalkyltriphenylphosphonium salts were prepared by the optical resolution of their 2,3-di-O-benzoyltartrates.The reaction of these salts with butyllithium afforded the corresponding ylides, which reacted with aldehydes to gi
Synthesis and Reaction of Optically Active 2- and 3-Hydroxyalkylphosphonium Salts
Yamamoto, Shin-ichi,Takeuchi, Hiroshi,Tanaka, Yuichiro,Okuma, Kentaro
, p. 113 - 116 (2007/10/02)
Epoxides were converted to the corresponding optically active 2- and 3-hydroxyalkylphosphonium salts by the reaction with triphenylphosphine and dibenzoyltartaric acid (or camphorsulfonic acid), and with methylenetriphenylphosphorane and this acid, follow
