Optical Resolution of 2- and 3-Hydroxyalkyltriphenylphosphonium Salts. Stereoselective Synthesis of Enantiomerically Pure (E)- and (Z)-Homoallylic Alcohols

DOI: 10.1246/bcsj.66.2623

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2623 - 2632 (1993)

Update date:2022-08-03

Topics:

Authors:

Okuma, Kentaro

Tanaka, Yuichiro

Ohta, Hiroshi

Matsuyama, Haruo

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Article abstract of DOI:10.1246/bcsj.66.2623

Optically active 2- and 3-hydroxyalkyltriphenylphosphonium salts were prepared by the optical resolution of their 2,3-di-O-benzoyltartrates.The reaction of these salts with butyllithium afforded the corresponding ylides, which reacted with aldehydes to gi

Full text of DOI:10.1246/bcsj.66.2623

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Product name:(2S,3S)-2,3-Bis-benzoyloxy-3-carboxy-propionate((R)-3-hydroxy-butyl)-triphenyl-phosphonium;

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