155501-29-4

Upstream product

• 169560-24-1 3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>prop-1-ene 
• 139590-84-4 (1S,6R)-1-Allyl-6-(toluene-4-sulfinyl)-bicyclo[4.1.0]heptane 
• 140629-82-9 3-<(1S,6R)-6-((S)-p-tolylsulfinyl)bicyclo<4.1.0>hept-1-yl>prop-1-ene 

Downstream Products

• 180524-19-0 3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>heptan-1-yl>propanal 
• 180524-20-3 (E)-2-Methyl-5-((1S,6R)-6-p-tolylsulfanyl-bicyclo[4.1.0]hept-1-yl)-pent-2-enoic acid methyl ester 
• 180524-15-6 2-[(S)-6-p-Tolylsulfanyl-spiro[4.5]dec-6-en-(2E)-ylidene]-propionic acid methyl ester 
• 186357-52-8 C₂₀H₂₆O₃S 
• 180524-22-5 2-[(S)-6-(Toluene-4-sulfonyl)-spiro[4.5]dec-6-en-(2E)-ylidene]-propan-1-ol 
• 180524-21-4 2-[(S)-6-(Toluene-4-sulfonyl)-spiro[4.5]dec-6-en-(2E)-ylidene]-propionic acid methyl ester 
• 186357-57-3 Formic acid 2-[(S)-6-(toluene-4-sulfonyl)-spiro[4.5]dec-6-en-(2E)-ylidene]-propyl ester 
• 180524-16-7 (2R,5S)-2-Isopropenyl-6-(toluene-4-sulfonyl)-spiro[4.5]dec-6-ene 
• 139590-77-5 3-<(1S)-1-methyl-2-(p-tolylthio)cyclohex-2-en-1-yl>propyl acetate 
• 139590-78-6 3-<(1S)-1-iodomethyl-2-(p-tolylthio)cyclohex-2-en-1-yl>propyl acetate 
• 139590-81-1 3-<(1S,6S)-5-allyl-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>propyl acetate 
• 140421-06-3 ethyl (E)-5-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>heptan-1-yl>-2-pentenoate 
• 139590-74-2 3-<(1S,6R)-6-(p-tolylthio)bicyclo<4.1.0>hept-1-yl>propyl acetate 
• 140421-07-4 ethyl <(5R)-6-(p-tolylthio)spiro<4.5>dec-6-en-2-yl>acetate 

Relevant academic research and scientific papers

Regioselective functionalization of the methylene group adjacent to cyclopropyl sulfide via mercury(II)-mediated regioselective ring-opening reaction

A regioselective bond-cleavage of the cyclopropyl sulfide (2) was performed with mercury(11) salt to supply the homoallyl anion synthon (3) bearing two reactive sites at the α and δ positions. The reaction of 3 with n-Bu3SnH and l2 g

A Sulfur-assisted Regioselective α-Functionalization of Cyclopropyl Sulfides. Synthetic Applications of Homoallyl Anion Synthon

γ,δ-Unsaturated γ-sulfenyl or sulfinylalkylmercury chlorides 5 and 15, generated from the cyclopropyl sulfide 7 and mercury(II) trifluoroacetate, were demonstrated to be homoallyl anion synthons; these compounds recyclized into the α-functionalized cyclop

Novel Asymmetric Cyclopropanation Utilizing Sulfinyl Chirality: Application to Construction of a Spirodecane System

An optically active vinylic sulfoxide is stereoselectively transformed into a chiral cyclopropane by means of a Michael addition reaction with an allyl Grignard reagent, and using this novel cyclopropanation, asymmetric construction of a spirodecane