155532-86-8Relevant academic research and scientific papers
Approach to phenanthroindolizidine alkaloids using organic azides with 1- Aryl allylic alcohols: Unexpected tandem reactions to indenyl aziridines via nazarov cyclization
Yokoi, Taiki,Sugiura, Takahiro,Tanimoto, Hiroki,Morimoto, Tsumoru,Nishiyama, Yasuhiro,Kakiuchi, Kiyomi
, p. 1313 - 1327 (2016)
Organic azide cyclization reactions with 1- Aryl allylic alcohols were investigated in a synthetic study of phenanthroindolizidine alkaloids. Unsaturated imines (enimines) were effectively obtained from the allylic alcohol adjacent to electron-rich aromat
A convenient alternative route to β-aminoketones
San Martin,De Marigorta,Dominguez
, p. 2255 - 2264 (2007/10/02)
Enaminones has been prepared and submitted to conjugate reduction with LAH and the system Al2O3/R2NH to give β-aminoketones. The latter tandem amination system has also been applied in the Mannich reaction, improving the synthesis of several new diaryl β-aminoketones. Besides, the sequential use of DMFDMA and LAH-CuI on deoxybenzoins furnishes a new route for the synthesis of enones.
