15560-99-3

Basic information

• Product Name: Butyl 2-methylphenyl sulfide
• Synonyms: 1-[(2-Methylphenyl)thio]butane;Butyl 2-methylphenyl sulfide;Butyl(2-methylphenyl) sulfide;Butyl(o-tolyl) sulfide
• CAS NO: 15560-99-3
• Molecular Formula: C₁₁H₁₆S
• Molecular Weight: 180.31
• Mol File: 15560-99-3.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 120 °C(Press: 12 Torr)
• Appearance: /
• Density: 0.96±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Butyl 2-methylphenyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: Butyl 2-methylphenyl sulfide(15560-99-3)
• EPA Substance Registry System: Butyl 2-methylphenyl sulfide(15560-99-3)

Safety Data

• Hazardous Substances Data: 15560-99-3(Hazardous Substances Data)

Upstream product

• 109-69-3 n-Butyl chloride 
• 137-06-4 2-thiocresol 
• 109-79-5 n-butanethiol 
• 66107-34-4 2-methylphenyl triflate 
• 615-37-2 ortho-methylphenyl iodide 
• 629-45-8 dibutyl disulfide 
• 133-59-5 Toluene-2-sulfonyl chloride 
• 95-46-5 2-methylphenyl bromide 
• 542-69-8 1-iodo-butane 

Downstream Products

• 84321-29-9 1-(butylsulfinyl)-2-methylbenzene 
• 1205-39-6 N-phenyl-2-methylaniline 
• 104741-61-9 3-Methyl-4-butyl-mercapto-benzaldehyd 
• 105837-91-0 3-Methyl-4-butylmercapto-benzylmercaptan 
• 97833-72-2 Butyl-<4-butylmercapto-3-methyl-benzyl>-sulfid 
• 15560-07-3 2-(4-Butylsulfanyl-3-methyl-phenyl)-N-hydroxy-acetamide 
• 15560-21-1 (4-Butylsulfanyl-3-methyl-phenyl)-acetic acid ethyl ester 
• 15560-14-2 1-(4-butylsulfanyl-3-methyl-phenyl)-ethanone 
• 109221-58-1 3-Methyl-4-butyl-mercapto-benzylchlorid 

Relevant articles and documents

Ullmann-type: N-arylation of anilines with alkyl(aryl)sulfonium salts

A palladium/copper-cocatalyzed Ullmann-type N-arylation of anilines using alkyl(aryl)sulfonium triflates as arylation reagents has been accomplished. The reaction enabled Caryl-S bond cleavage over Calkyl-S bond breakage of alkyl(aryl)sulfoniums by Pd(P(tBu)3)2/CuI and gave the corresponding N-arylated products in good to high yields. It was also significant that the reactions of aniline with asymmetric butyl(mesityl)(aryl)sulfonium triflates showed excellent selectivity, in which the aryl groups other than the bulky and electron-rich mesityl moieties were transformed.

Cu-catalyzed coupling of aryl iodides with thiols using carbonyl-phosphine oxide ligands

A series of carbonyl-phosphine oxide ligands were synthesized from 2-bromophenylaldehyde and used in Cu-catalyzed C-S coupling reactions. Aryl iodide and aryl bromide reacted with thiols efficiently upon catalysis under mild reaction conditions and a yiel

L-proline-promoted CuI-catalyzed C-S bond formation between aryl iodides and thiols

An improved, mild procedure for the CuI-catalyzed coupling reactions of aryl iodides with aliphatic and aromatic thiols, using L-proline as the ligand, is reported. This procedure is noteworthy given its high generality and exceptional level of functional group toleration. Copyright Taylor & Francis Group, LLC.