155626-96-3

Upstream product

• 18742-02-4 2-bromo-2-(2-ethyl)dioxolane 
• 155627-09-1 ethyl <4-(methoxy)methoxy>phenylacetate 
• 17138-28-2 (4-hydroxy-phenyl)-acetic acid ethyl ester 

Downstream Products

• 155626-98-5 1-benzyloxy-4-(1,3-dioxolan-2-yl)-2-(4-methoxymethoxyphenyl)butane 
• 155627-00-2 7-Benzyloxy-2-diazo-6-(4-hydroxy-phenyl)-heptan-3-one 
• 94194-08-8 4-(4-acetoxyphenyl)-5-benzyloxypentanoic acid 
• 155627-08-0 5-Benzyloxy-4-(4-hydroxy-phenyl)-pentanal 
• 155626-97-4 4-[1,3]Dioxolan-2-yl-2-(4-methoxymethoxy-phenyl)-butan-1-ol 

Relevant academic research and scientific papers

Synthetic studies on aphidicolane and stemodane diterpenes. II. Neighboring hydroxyl group participation in stereoselective syntheses of tricyclo[6.3.1.01,6]dodecanes corresponding to the B/C/D-ring systems

Tricyclo[6.3.1.01,6]dodecane derivatives (5 and 6) corresponding to the B/C/D-ring systems of aphidicolane and stemodane diterpenes were synthesized stereoselectively via a spirodienone-alcohol (4) as a common intermediate. Participation of the neighboring hydroxyl group in 4 is crucial for controlling the stereochemistry of the spirocenters.