1558025-16-3Relevant academic research and scientific papers
Silver-mediated radical aryltrifluoromethylthiolation of activated alkenes by S-trifluoromethyl 4-methylbenzenesulfonothioate
Zhao, Xia,Yang, Bo,Wei, Aoqi,Sheng, Jianqiao,Tian, Miaomiao,Li, Quan,Lu, Kui
supporting information, p. 1719 - 1722 (2018/04/02)
Herein, we describe the preparation of trifluoromethylthiol-substituted oxindoles by silver-mediated aryltrifluoromethylthiolation of activated alkenes, using S-trifluoromethyl 4-methylbenzenesulfonothioate as a F3CS radical source and showing that the reagent availability, mild conditions, and broad functional group compatibility of this transformation make it a viable alternative strategy of constructing Csp3–SCF3 bonds.
Silver-mediated radical aryltrifluoromethylthiolaton of activated alkenes
Yin, Feng,Wang, Xi-Sheng
supporting information, p. 1128 - 1131 (2014/03/21)
The first example of silver-mediated oxidative aryltrifluoromethylthiolation of activated alkenes to produce valuable trifluoromethylthiole-containing oxindoles was developed. Mechanistic investigations indicated that this novel transformation proceeded through a unique F3CS? radical addition path, thus providing a practical and easy-handling method to generate a F3CS ? radical in the laboratory.
