1558046-43-7

Basic information

• Product Name: (+)-2,3,14-triepi-chaetominine
• CAS NO: 1558046-43-7
• Molecular Weight: 402.409
• Mol File: 1558046-43-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (+)-2,3,14-triepi-chaetominine(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-2,3,14-triepi-chaetominine(1558046-43-7)
• EPA Substance Registry System: (+)-2,3,14-triepi-chaetominine(1558046-43-7)

Safety Data

• Hazardous Substances Data: 1558046-43-7(Hazardous Substances Data)

Upstream product

• 72144-94-6 3-indol-3-yl-2-(4-oxo-4H-quinazolin-3-yl)-propionic acid 
• 85612-29-9 N_b-(2-aminobenzoyl)-L-tryptophan methyl ester 
• 1190112-03-8 C₁₉H₁₅N₃O₃ 
• 205042-94-0 N-(2-aminobenzoyl)-D-tryptophan methyl ester 
• 7524-52-9 (S)-tryptophan methyl ester hydrochloride 
• 118-48-9 isatoic anhydride 
• 14907-27-8 (R)-(+)-tryptophan methyl ester hydrochloride 
• 1602783-27-6 (S)-2-[(S)-3-(1H-indol-3-yl)-2-(4-oxo-4H-quinazolin-3-yl)propionylamino]propionic acid methyl ester 
• 1173180-37-4 (S)-2-[(R)-3-(1H-indol-3-yl)-2-(4-oxo-4H-quinazolin-3-yl)-proprionylamino]propionic acid methyl ester 
• 1190111-93-3 (R)-3-(1H-indol-3-yl)-2-(4-oxo-4H-quinazolin-3-yl)-propionic acid methyl ester 
• 1602783-25-4 methyl (S)-{2-[(S)-3-(1H-indol-3-yl)-2-(2-nitrobenzamido)propanamido]propanoate} 
• 1558046-41-5 methyl (S)-{2-((3R,4aR,9aS)-4a-hydroxy-2-oxo-3-(4-oxoquinazolin-3(4H)-yl)-2,3,4,4a,9,9a-hexahydro-1H-pyrido[2,3]indol-1-yl)propanoate} 
• 27261-93-4 (S)-3-(1H-indol-3-yl)-2-(2-nitrobenzamido)propanoic acid 
• 610-14-0 2-nitrobenzyl chloride 

Relevant articles and documents

Biomimetic synthesis of (-)-chaetominine epimers via copper-catalyzed radical cyclization

Synthetic endeavors toward (-)-chaetominine via copper-catalyzed radical cyclization are reported. Both of the pyrido[2,3,b]-indole ring (C ring) and imidazolidinone (D ring) are efficiently constructed in one-pot manner. It's unveiled that the newly form

Complexity generation by chemical synthesis: A five-step synthesis of (-)-chaetominine from l-tryptophan and its biosynthetic implications

We demonstrated, for the first time, that on the basis of chemistry principles, the hexacyclic peptidyl alkaloid (-)-chaetominine (1) can be synthesized in a straightforward manner from l-Trp. The approach features the efficient generation of molecular complexity via a tandem C3/C14 syn-selective epoxidation (dr = 3:2)-annulative ring-opening reaction and a regioselective epimerization at C14. The successful production of (-)-chaetominine (1) from l-Trp could be helpful for revealing how the configuration of l-tryptophan becomes inverted in the biosynthetic pathway of (-)-chaetominine (1). This journal is the Partner Organisations 2014.