1558056-36-2Relevant academic research and scientific papers
Synthesis of phosphorus containing medium ring heterocycles by sequential Claisen rearrangement and ring closing metathesis
Majumdar,Nandi, Raj Kumar,Ganai, Sintu
, p. 1247 - 1250 (2014/02/14)
An efficient method for the synthesis of novel medium ring phosphorus containing heterocycles starting from phenol derivatives by ruthenium catalyzed ring closing metathesis is described. This work deals with a sequential aromatic Claisen-rearrangement, coupling of an allyl/vinyl phosphonate, and ring closing metathesis reaction. All of these reactions were carried out at ambient temperature to afford the medium-sized phosphorus heterocycles in excellent yields.
