155806-35-2

Basic information

• Product Name: (R)-(S)-JOSIPHOS
• Synonyms: JOSIPHOS SL-J001-1;(R)1[(1S)2(diphenylphosphino)ferrocenyl] et-dicyclohexylphos;(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl];(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphineethanoladduct,min.97%(R)-(S)-JOSIPHOS;(r,r)-1-[1-(dicyclohexylphosphino)ethyl]-2-o-(diphenylphosphino)ferrocene (acc to cas);(R)-(S)-Josiphos, Josiphos SL-J001-1, (2R)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS);(R)-1-[(SP)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine;(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl] ethyldicyclohexylphosphine ethanol adduct
• CAS NO: 155806-35-2
• Molecular Formula: C36H44FeP2 10*
• Molecular Weight: 594.53
• Product Categories: organophosphine ligand;Chiral Phosphine;Ferrocene Series;Josiphos Series
• Mol File: 155806-35-2.mol
• Article Data: 0

Chemical Properties

• Melting Point: ~95 °C (dec.)
• Appearance: White/Crystals or Crystalline Powder
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Stability: store cold
• CAS DataBase Reference: (R)-(S)-JOSIPHOS(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(S)-JOSIPHOS(155806-35-2)
• EPA Substance Registry System: (R)-(S)-JOSIPHOS(155806-35-2)

Safety Data

• Statements: 36/37/38
• Safety Statements: 24/25
• WGK Germany: 3
• F: 10
• Hazardous Substances Data: 155806-35-2(Hazardous Substances Data)

Usage

Chemical Properties

orange crystalline powder

Uses

It may be used in the preparation of cyclopentadienyliridium complexes, [IrCl(PP)]2 and [IrCp(PP)]. (Cp= cyclopentadienyl; PP= (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine)

General Description

sold in collaboration with Solvias AG

InChI:InChI=1/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m1../s1