155829-46-2

Basic information

• Product Name: RuCl(CO)(glycinate)(PPh₃)2
• CAS NO: 155829-46-2
• Molecular Weight: 763.174
• Mol File: 155829-46-2.mol

Chemical Properties

• CAS DataBase Reference: RuCl(CO)(glycinate)(PPh₃)2(CAS DataBase Reference)
• NIST Chemistry Reference: RuCl(CO)(glycinate)(PPh₃)2(155829-46-2)
• EPA Substance Registry System: RuCl(CO)(glycinate)(PPh₃)2(155829-46-2)

Safety Data

• Hazardous Substances Data: 155829-46-2(Hazardous Substances Data)

Upstream product

• 157072-60-1 (carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) 
• 56-40-6 glycine 

Relevant articles and documents

Metal Complexes of Biologically Important Ligands, LXX. - Synthesis, Stereochemistry and Reactions of Ruthenium(II) and Osmium(II) Complexes with α-Amino Carboxylates

The reactions of MHCl(CO)(PPh3)3 with salts of α-amino acids give the hydrido-N,O-chelate complexes MH(CO)(NH2CHRCOO)(PPh3)2 (1a-g; M = Ru, Os).Complexes 1a-c can alternatively be prepared by oxidative addition of the appropriate α-amino acid to Ru(CO)3(PPh3)2.The crystal structure of 1b has been determined by an X-ray structural analysis.The leucinato compound 1c is an effective catalyst for the decomposition of formic acid.In contrast, reactions of RuHCl(CO)(PPh3)3 with α-amino acids afford the chloro-N,O-chelate complexes RuCl(CO)(NH2CHRCOO)(PPh3)2 2a-h.The decomposition reactions of 2c, 2g and 2h have been investigated. - Key Words: Ruthenium complexes / Osmium complex / Hydrido complexes / α-Amino acids / Oxidative Addition