1558818-52-2Relevant academic research and scientific papers
Copper-catalysed three-component carboiodination of arynes: Expeditious synthesis of: O -alkynyl aryl iodides
Cao, Wenxuan,Niu, Sheng-Li,Shuai, Li,Xiao, Qing
supporting information, p. 972 - 975 (2020/02/03)
A copper-catalysed three-component iodoalkynylation reaction of arynes for the expeditious and versatile synthesis of o-alkynyl aryl iodides has been developed. Mechanism research shows that the reaction goes through two steps enabled by copper catalysis: the formation of 1-iodo-2-arylacetylene and the insertion of the aryne into a C(sp)-I bond.
Diaceno[a,e]pentalenes from homoannulations of o-alkynylaryliodides utilizing a unique Pd(OAc)2/n-Bu4NOAc catalytic combination
Shen, Junjian,Yuan, Dafei,Qiao, Yan,Shen, Xingxing,Zhang, Zhongbo,Zhong, Yuwu,Yi, Yuanping,Zhu, Xiaozhang
, p. 4924 - 4927 (2015/04/27)
A heterogeneous catalytic system, Pd(OAc)2/n-Bu4NOAc, for the efficient synthesis of diaceno[a,e]pentalenes via a tandem Pd catalytic cycle is reported. The catalytic partner n-Bu4NOAc played indispensable and versatile ro
Synthesis of tetracyclic chromenones via platinum(ii) chloride catalysed cascade cyclization of enediyne-enones
Sivaraman, Mahalingam,Perumal, Paramasivan T.
, p. 1318 - 1327 (2014/03/21)
PtCl2 catalysed cascade cyclization of an enediyne-enone system to afford a tetracyclic chromenone is reported, which proceeds through two consecutive highly regioselective 6-endo-dig cyclizations in a single step with the formation of two new C-C bonds and two new rings in excellent yield. A mechanism for this transformation is proposed based on the isolated intermediates.
