1559077-98-3Relevant academic research and scientific papers
Room temperature decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids by photoredox catalysis
Xu, Pan,Abdukader, Ablimit,Hu, Kaidong,Cheng, Yixiang,Zhu, Chengjian
supporting information, p. 2308 - 2310 (2014/03/21)
A visible-light-induced decarboxylative trifluoromethylation of α,β-unsaturated carboxylic acids, which uses the Togni reagent as the CF3 source is disclosed. The corresponding trifluoromethylated alkenes were obtained in moderate to high yields with excellent functional group tolerance at ambient temperature. Preliminary mechanistic analyses suggest a radical-type mechanism. The Royal Society of Chemistry 2014.
