156050-40-7

Basic information

• Product Name: 2-(2-Chloro-2-phenyl-ethylsulfanyl)-benzothiazole
• CAS NO: 156050-40-7
• Molecular Weight: 305.852
• Mol File: 156050-40-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(2-Chloro-2-phenyl-ethylsulfanyl)-benzothiazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Chloro-2-phenyl-ethylsulfanyl)-benzothiazole(156050-40-7)
• EPA Substance Registry System: 2-(2-Chloro-2-phenyl-ethylsulfanyl)-benzothiazole(156050-40-7)

Safety Data

• Hazardous Substances Data: 156050-40-7(Hazardous Substances Data)

Upstream product

• 149-30-4 2-Mercaptobenzothiazole 
• 100-42-5 styrene 
• 33405-92-4 2-benzothiazolylsulfenyl chloride 

Downstream Products

• 156050-41-8 2-(2-Chloro-2-phenyl-ethanesulfonyl)-benzothiazole 
• 3780-00-5 1-(3-phenyl-1,2-propadienyl)benzene 
• 156049-96-6 (E)-2-<(2-phenylethenyl)sulfonyl>benzothiazole 

Relevant articles and documents

Stereochemistry of direct olefin formation from carbonyl compounds and lithiated heterocyclic sulfones

The conditions for the title reaction were studied for the 2-benzothiazole and 2-pyridine series and for some examples in the 2-pyrimidine series.The olefin preparations were generally observed to be more efficient for 2-BT-sulfone systems.From the data of the hundred cases studied, it can be concluded that (E)-olefins are obtained: (i) from saturated BT-sulfones and aromatic aldehydes; and (ii) from benzylic BT-sulfones and branched saturated aldehydes (isobutyraldehyde, pivalaldehyde) or α,β-ethylenic or aromatic aldehydes. (Z)-olefins arise: (i) fom propargylic BT-sulfones and saturated or aromatic aldehydes; and (ii) from allylic or benzylic Pyr-sulfones and saturated aldehydes.Possible mechanisms for this new olefination procedure were examined. - heteroaromatic sulfones, organolithium derivatives, intramolecular ipso reactions, stereochemistry, elimination, olefination.