156086-76-9Relevant academic research and scientific papers
Use of mixed Li/K metal TMP amide (LiNK chemistry) for the synthesis of [2.2]metacyclophanes
Blangetti, Marco,Fleming, Patricia,O'Shea, Donal F.
, p. 1249 - 1254 (2011)
A new two-step general approach to [2.2]metacyclophane synthesis from substituted m-xylenes is described. The strategy employs a selective benzylic metalation and oxidative C-C bond formation for both synthetic operations. Regioselective benzylic metalati
