Beilstein Journal of Organic Chemistry p. 1249 - 1254 (2011)
Update date:2022-07-30
Topics:
Blangetti, Marco
Fleming, Patricia
O'Shea, Donal F.
A new two-step general approach to [2.2]metacyclophane synthesis from substituted m-xylenes is described. The strategy employs a selective benzylic metalation and oxidative C-C bond formation for both synthetic operations. Regioselective benzylic metalati
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