156093-12-8Relevant articles and documents
Tandem Enyne Allene-Radical Cyclization: Low-Temperature Approaches to Benz[e]indene and Indene Compounds
Grissom, Janet Wisniewski,Klingberg, Detlef,Huang, Dahai,Slattery, Brian J.
, p. 603 - 626 (2007/10/03)
In an effort to lower the temperatures required to prepare multicyclic compounds using the tandem enediyne-radical cyclization, we have developed the tandem enyne allene-radical cyclization which proceeds at temperatures as low as 37°C. The reactions were
High temperature radical cyclization anomalies in the tandem enediyne-bis-radical cyclization
Grissom, Janet Wisniewski,Calkins, Trevor L.,Huang, Dahai,McMillen, Heidi
, p. 4635 - 4650 (2007/10/02)
Previous reports have shown that the thermolysis of aromatic enediynes containing radical accepting tethers will undergo tandem enediyne-radical cyclizations. Herein will be reported several examples of the tandem enediyne-bis-radical cyclization where no
