15614-85-4

Upstream product

• 57693-96-6 cis-Mn(CO)4Br(PPh₃)2 
• 101-02-0 triphenyl phosphite 
• 14516-54-2 bromopentacarbonylmanganese(I) 
• 15614-85-4 mer-tricarbonylbromobis(triphenylphosphite)manganese(I) 
• 15614-85-4 fac-tricarbonylbromobis(triphenylphosphite)manganese(I) 

Downstream Products

• 87969-16-2 mer-Tricarbonyl-trans-bis(triphenylphosphit)(triphenylstannandithiocarboxylato-S)mangan(I) 
• 65035-20-3 (η5-1-bromoindenyl)tricarbonylmanganese(I) 
• 79634-54-1 (η5-1-bromoindenyl)dicarbonyl(triphenylphosphite)manganese(I) 
• 15614-85-4 fac-tricarbonylbromobis(triphenylphosphite)manganese(I) 
• 15614-85-4 mer-tricarbonylbromobis(triphenylphosphite)manganese(I) 
• 117686-85-8 trans-Mn(CO)4{P(OPh)3}2BF₄ 
• 16923-76-5 mer,trans-HMn(CO)3{P(OPh)3}2 
• 14244-51-0 sodium bis(triphenylphosphite)tricarbonylmanganate 
• 114129-81-6 tetra-n-butylammonium bis(triphenylphosphite)tricarbonylmanganate 
• 103190-12-1 Mn(CO)3((C₆H₅)2PC(S)NCH₃)((C₆H₅O)3P) 

Relevant academic research and scientific papers

Synthetic studies on the preparation of [Mn(CO)3{P(OR)3}{κ2-S,S′-Ph2P(S)NP(S)Ph2}], R?= Ph, Et

Complexes [Mn(CO)3P(OR)3{κ2-S,S′-Ph2P(S)NP(S)Ph2}], R = Ph, Et were prepared using four reaction routes. P(OPh)3 presented similar electronic properties to CO in substitution reactions. Tri

Synthesis of Cationic Mer-Phosphite-Substituted Carbonylmanganese Compounds

Di-, tri- and tetrasubstituted carbonylmanganese compounds (OC)nL6-nMn(+)PF6(-) (L = P(OMe)3, P(OEt)3, P(O-i-Pr)3, P(OPh)3 and P(O-o-Tolyl)3) are synthesized by hydride abstraction and substitution processes from corresponding hydridemanganese compounds. - Key words: Phosphite Substitution, Carbonylmanganese Cations, Hydride Abstraction