15619-18-8

Basic information

• Product Name: 4α-tert-Butylcyclohexane-1β-carbonitrile
• Synonyms: 4α-tert-Butylcyclohexane-1β-carbonitrile
• CAS NO: 15619-18-8
• Molecular Formula: C₁₁H₁₉N
• Molecular Weight: 165.27526
• Mol File: 15619-18-8.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 251.1±9.0 °C(Predicted)
• Appearance: /
• Density: 0.88±0.1 g/cm3(Predicted)
• CAS DataBase Reference: 4α-tert-Butylcyclohexane-1β-carbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 4α-tert-Butylcyclohexane-1β-carbonitrile(15619-18-8)
• EPA Substance Registry System: 4α-tert-Butylcyclohexane-1β-carbonitrile(15619-18-8)

Safety Data

• Hazardous Substances Data: 15619-18-8(Hazardous Substances Data)

Upstream product

• 74-90-8 hydrogen cyanide 
• 2228-98-0 4-tert-butylcylohexene 
• 61827-31-4 1-(1-Cyano-4-tert-butylcyclohexyl)-2-carbomethoxyhydrazine 
• 20691-52-5 1-carboxaldehyde-4-(1,1-dimethylethyl)-cyclohexane 
• 83859-38-5 carbomethoxyhydrazone of 4-tert-butylcyclohexanone 
• 143-33-9 sodium cyanide 
• 33670-05-2 C₁₃H₂₁N₃O₂ 

Downstream Products

• 105906-07-8 1-trans-(4-t-butylcyclohexyl)-acetic acid 

Relevant articles and documents

OXIDATIVE CONVERSION OF ALIPHATIC ALDEHYDES TO NITRILES USING OXOAMMONIUM SALT

The present invention relates to an oxidative transformation method of aliphatic benzaldehydes to nitriles using NH_4OAc through oxoammonium salts. By using stoichiometric amounts of oxoammonium salts to establish optimal reaction conditions associated with the oxidative conversion of aliphatic benzaldehydes to nitriles, high yields of nitrile can be selectively obtained, and the oxoammonium salts used can be oxidized and reused in a simple method.COPYRIGHT KIPO 2020

Oxoammonium salt-mediated oxidative nitriles synthesis from aldehydes with ammonium acetate

An efficient and scalable route for the synthesis of nitriles was developed by oxoammonium salt (4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate) mediated oxidative conversion of aldehydes with NH4OAc. A variety of aliphatic aldehydes as well as benzaldehydes were converted into the corresponding nitriles in high yields. The nitroxyl radical which is the reduced species of the used oxoammonium salt was recovered by simple acid-base extraction for the recycling.

Electrochemical oxidation of ketone acylhydrazones and their HCN adducts in NaCN-MeOH. Tranformation of ketones to nitriles

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