156257-14-6Relevant articles and documents
Synthesis, crystal structure, IR and Raman properties of 1,2-diacetamidocyclohexane and its complexes with ZnBr2 and HBr 3
Bekaert,Lemoine,Viossat,Jouan,Gemeiner,Brion
, p. 39 - 44 (2005)
X-ray crystallography, infrared absorption and Raman scattering were applied to study the influence of Zn(II) or H+ on the amidic bond. (R,R)-1,2-diacetamidocyclohexane (DAACH) was chosen as a conformationally strained chiral building block inc
Supramolecular-directed chiral induction in biaryl derivatives
Etxebarria,Degenbeck,Felten,Serres,Nieto,Vidal-Ferran
supporting information; experimental part, p. 8794 - 8797 (2010/03/04)
(Chemical Equation Presented) A thermodynamically controlled resolution has allowed for the generation of diastereomerically enriched complexes, by chirality transfer from an enantiopure building block to a dynamically racemic biaryl derivative. A switcha
N,N'-dialkylated 1,2-diamine derivatives as new efficient ligands for RuCl2(PPh3)3 catalyzed asymmetric transfer hydrogenation of aromatic ketones
Kim, Geon-Joong,Kim, Sang-Han,Chong, Pong-Hyun,Kwon, Mi-Ae
, p. 8059 - 8062 (2007/10/03)
Chiral N,N'-dialkylated cyclohexanediamine derivatives ligands have been synthesized and used in an asymmetric transfer hydrogenation of aryl ketones. Optically active alcohols with up to 93% enantiomeric excess were obtained in high yield.