156267-11-7

Basic information

• Product Name: 5-methoxy-2-methyl-N-methylaniline
• Synonyms: 5-methoxy-2-methyl-N-methylaniline
• CAS NO: 156267-11-7
• Molecular Weight: 151.208
• Mol File: 156267-11-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 5-methoxy-2-methyl-N-methylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methoxy-2-methyl-N-methylaniline(156267-11-7)
• EPA Substance Registry System: 5-methoxy-2-methyl-N-methylaniline(156267-11-7)

Safety Data

• Hazardous Substances Data: 156267-11-7(Hazardous Substances Data)

Upstream product

• 54788-38-4 2-chloro-4-methoxy-1-methylbenzene 
• 593-51-1 methylamine hydrochloride 
• 156267-17-3 (5-Methoxy-2-methyl-phenyl)-carbamic acid benzyl ester 
• 156267-21-9 (5-Methoxy-2-methyl-phenyl)-methyl-carbamic acid benzyl ester 

Downstream Products

• 7703-91-5 6-methoxy-1-methylindolin-2-one 
• 6265-13-0 4-methyl-3-(methylamino)phenol 
• 1051897-32-5 N-(3,5-dimorpholin-4-ylphenyl)-N'-(5-methoxy-2-methyl-phenyl)-N'-methyl-pyrimidine-2,4-diamine 
• 158719-26-7 2,2'-dithiobis [N-phenyl-6-acetoxy-1-methylindolyl-3-carboxamide] 
• 1026065-90-6 Acetic acid 1-methyl-3-phenylcarbamoyl-2-thioxo-2,3-dihydro-1H-indol-6-yl ester 
• 13383-73-8 6-hydroxy-1-methyl-indolin-2-one 

Relevant articles and documents

Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts

We report the palladium-catalyzed coupling of aryl halides with ammonia and gaseous amines as their ammonium salts. The coupling of aryl chlorides and ortho-substituted aryl bromides with ammonium sulfate forms anilines with higher selectivity for the primary arylamine over the diarylamine than couplings with ammonia in dioxane. The resting state for the reactions of aryl chlorides is different from the resting state for the reactions of aryl bromides, and this change in resting states is proposed to account for a difference in selectivities for reactions of the two haloarenes.