156278-52-3Relevant academic research and scientific papers
Conversion of 1-(ω-Alkynyl)-1,2-propadienyl Sulfides to Bicyclic Dienones by the Use of Iron Carbonyl Complex
Narasaka, Koichi,Shibata, Takanori
, p. 315 - 318 (1994)
1-(ω-Alkenyl)-1,2-propadienyl sulfide reacts with Fe(CO)4(NMe)3 under photo irradiation conditions and a cyclized and carbonylated η3-allyl mononuclear iron complex is isolated.On the other hand, the reaction of 1-(ω-alkynyl)-1,2-propadienyl sulfides and Fe(CO)4(NMe)3 also proceeds by photo irradiation to give various bicyclic dienones through the η3-allyl iron complex.
