Conversion of 1-(ω-Alkynyl)-1,2-propadienyl Sulfides to Bicyclic Dienones by the Use of Iron Carbonyl Complex

DOI: 10.1246/cl.1994.315

Source and publish data:

Chemistry Letters p. 315 - 318 (1994)

Update date:2022-08-04

Topics:

Authors:

Narasaka, Koichi

Shibata, Takanori

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1994.315

1-(ω-Alkenyl)-1,2-propadienyl sulfide reacts with Fe(CO)4(NMe)3 under photo irradiation conditions and a cyclized and carbonylated η³-allyl mononuclear iron complex is isolated.On the other hand, the reaction of 1-(ω-alkynyl)-1,2-propadienyl sulfides and Fe(CO)4(NMe)3 also proceeds by photo irradiation to give various bicyclic dienones through the η³-allyl iron complex.

Full text of DOI:10.1246/cl.1994.315

Products guided by the article

Product name:Fe(CO)3(CHCOC(C₆H₅)C(C₃H₆CHSCH₃)C)

Cas No:156278-52-3

R&D Labs maybe for 156278-52-3

Changzhou Sunlight Pharmaceutical Co., Ltd.

Contact:+86-519-83131668;83139028;83138042;83137041

Address:JiuliStreet, Benniu Town Changzhou City, Jiangsu Province
Innua Petrochem Ltd.

Contact:+1-284-4950244

Address:Box 3069, Road Town, Tortola, British Virgin Islands
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
Tianjin Jingye Fine Chemicals Co., Ltd.

Contact:+86-15722078107; +86-22-26911407

Address:Bohua Fine Chemicals Base of Petrochemical Industry Park, Nanhuan Road, Dagang District, Tianjin, 300271, P. R. China

Relevant to this article

Synthesis and evaluation of some novel isochroman carboxylic acid derivatives as potential anti-diabetic agents

Doi:10.1016/j.ejmech.2009.03.009
(2009)
Synthetic applications of fluorinated phenyllithiums: Preparation of fluorinated α-methylstyrenes, benzhydrols, benzophenones and aryltrimethylsilanes

Doi:10.1016/0022-1139(96)03424-0
(1996)
Total syntheses of (-)-kopsifoline D and (-)-deoxoapodine: Divergent total synthesis via late-stage key strategic bond formation

Doi:10.1021/ja500548e
(2014)
Sonochemical Switching of Reaction Pathways in Solid-Liquid Two-phase Reactions

Doi:10.1039/c39840000439
(1984)
Synthesis, Biological Evaluation and in Silico Computational Studies of 7-Chloro-4-(1 H-1,2,3-triazol-1-yl)quinoline Derivatives: Search for New Controlling Agents against Spodoptera frugiperda (Lepidoptera: Noctuidae) Larvae

Doi:10.1021/acs.jafc.9b01067
(2019)
New Co-ordination Mode of 4,5-Dimercapto-1,3-dithiole-2-thionate(2-) in Polynuclear Gold(I) Complexes. Crystal Structures of 3-C3S5)(PPh3)3>ClO4 and

Doi:10.1039/DT9940001325
(1994)

Article Doi