Conversion of 1-(ω-Alkynyl)-1,2-propadienyl Sulfides to Bicyclic Dienones by the Use of Iron Carbonyl Complex

DOI: 10.1246/cl.1994.315

Source and publish data:

Chemistry Letters p. 315 - 318 (1994)

Update date:2022-08-04

Topics:

Authors:

Narasaka, Koichi

Shibata, Takanori

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Article abstract of DOI:10.1246/cl.1994.315

1-(ω-Alkenyl)-1,2-propadienyl sulfide reacts with Fe(CO)4(NMe)3 under photo irradiation conditions and a cyclized and carbonylated η³-allyl mononuclear iron complex is isolated.On the other hand, the reaction of 1-(ω-alkynyl)-1,2-propadienyl sulfides and Fe(CO)4(NMe)3 also proceeds by photo irradiation to give various bicyclic dienones through the η³-allyl iron complex.

Full text of DOI:10.1246/cl.1994.315

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