15630-06-5Relevant academic research and scientific papers
Organometallic chemistry of carbon-nitrogen multiple bonds. 4. Reductive coupling of iminium salts by nickel(0) reagents
Barefield, E. Kent,Carrier, Allen M.,Sepelak, Dennis J.,Van Derveer, Donald G.
, p. 1395 - 1399 (2008/10/08)
Reactions of [R2N=CH2]X (R = CH3, (CH3)2CHCH2; R2 = CH2(CH2CH2)2, O(CH2CH2)2; X = Cl-, Br
REAKTIONEN VON HETEROOLEFINEN AN ZENTRALMETALLEN IN NIEDRIGEN OXIDATIONSSTUFEN: STABILE ALDEHYDKOMPLEXE DES NICKEL(0) UND VERWANDTE VERBINDUNGEN
Walther, Dirk
, p. 393 - 402 (2007/10/02)
Nickel(0) complex moieties with a high electron density at the central atom are able to yield stable complexes with many aromatic aldehydes. 1H NMR spectroscopic data give evidence about olefin-like bonding of the aldehyde group and indicate a high charge transfer.Chelate ligands like tetramethylethylenediamine yield stable complexes of the composition (TME)NiL (L = aldehyde, benzil, α,β-unsaturated carbonyl compounds).Some reactions and properties of typical mixed ligand complexes are described.
