156340-25-9Relevant academic research and scientific papers
Intramolecular 1,6-hydride transfer in acyclic 1,6-diols: A mechanistic study
Gil, Juan F.,Ramon, Diego J.,Yus, Miguel
, p. 7307 - 7314 (1994)
The reaction of acyclic 1,6-diol 11a with 85% phosphoric acid at toluene reflux yields ketone 13a through an intramolecular 1,6-hydride transfer. This fact is proven by using a deuterated 1,6-diol (19), in which the corresponding 1,6-deuteride transfer oc
