Tetrahedron p. 7307 - 7314 (1994)
Update date:2022-08-02
Topics:
Gil, Juan F.
Ramon, Diego J.
Yus, Miguel
The reaction of acyclic 1,6-diol 11a with 85% phosphoric acid at toluene reflux yields ketone 13a through an intramolecular 1,6-hydride transfer. This fact is proven by using a deuterated 1,6-diol (19), in which the corresponding 1,6-deuteride transfer oc
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