156370-35-3Relevant academic research and scientific papers
Electrophile-induced Cyclisation-Fragmentation Reactions of Oxime O-Allyl and O-Benzyl Ethers
Grigg, Ronald,Markandu, Jasothara,Perrior, Trevor,Qiong, Zheng,Suzuki, Tekka
, p. 1267 - 1268 (1994)
Phenylselenyl bromide-induced cyclisation of γ- and δ-unsaturated aldoxime and ketoxime O-allyl and O-benzyl ethers is followed by a slow fragmentation furnishing cyclic imines which are readily reduced to pyrrolidines, piperidines or tetrahydroisoquinolines by sodium borohydride; dialkenyl oximes yield quinolizidines by an analogous sequence terminating in a mercury(II)-induced cyclization.
