
Journal of the Chemical Society. Chemical communications p. 1267 - 1268 (1994)
Update date:2022-08-05
Topics:
Grigg, Ronald
Markandu, Jasothara
Perrior, Trevor
Qiong, Zheng
Suzuki, Tekka
Phenylselenyl bromide-induced cyclisation of γ- and δ-unsaturated aldoxime and ketoxime O-allyl and O-benzyl ethers is followed by a slow fragmentation furnishing cyclic imines which are readily reduced to pyrrolidines, piperidines or tetrahydroisoquinolines by sodium borohydride; dialkenyl oximes yield quinolizidines by an analogous sequence terminating in a mercury(II)-induced cyclization.
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