156417-89-9Relevant academic research and scientific papers
Belt-Shaped Molecules by a Repetitive Synthetic Strategy
Josten, Wolfgang,Karbach, Detlef,Nieger, Martin,Voegtle, Fritz,Haegele, Klaus,et al.
, p. 767 - 778 (2007/10/02)
Belt-shaped molecules of the general type 2 containing up to five benzene ring units (cf. 37) have been synthesized by macrocyclisation reactions of ribbon-shaped precursors.An intermolecular cyclization step generates the macroheterocycles 38 and 40.The fourfold-bridged cyclophane 36 are prepared by intra- and intermolecular cyclization reactions.The X-ray structure analyses of 14, 16, 22, 23, 28, and 36 show S-shaped conformations of the molecules. - Key Words: Azaphanes / Cyclophanes / Macrocycles / Molecular belts / Multistep strategy
