1564224-75-4Relevant articles and documents
The development of carbon-carbon bond forming reactions of aminal radicals
Schiedler, David A.,Vellucci, Jessica K.,Lu, Yi,Beaudry, Christopher M.
, p. 1448 - 1465 (2015)
Aminal radicals were generated and used in synthetic reactions for the first time. Aminal radicals are formed from aminals by radical translocation using AIBN and a stoichiometric hydrogen atom donor, or by SmI2 reduction of N-acyl amidines or amidinium ions in the presence of a proton source. Aminal radicals were found to participate in inter- and intramolecular C-C bond forming reactions with electron deficient alkenes. Chemical yields were as high as 99%.