1564249-19-9

Basic information

• Product Name: (Z)-9-(1-p-tolylprop-1-enyloxy)-9-borabicyclo[3.3.1]nonane
• Synonyms: (Z)-9-(1-p-tolylprop-1-enyloxy)-9-borabicyclo[3.3.1]nonane
• CAS NO: 1564249-19-9
• Molecular Weight: 268.207
• Mol File: 1564249-19-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-9-(1-p-tolylprop-1-enyloxy)-9-borabicyclo[3.3.1]nonane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-9-(1-p-tolylprop-1-enyloxy)-9-borabicyclo[3.3.1]nonane(1564249-19-9)
• EPA Substance Registry System: (Z)-9-(1-p-tolylprop-1-enyloxy)-9-borabicyclo[3.3.1]nonane(1564249-19-9)

Safety Data

• Hazardous Substances Data: 1564249-19-9(Hazardous Substances Data)

Upstream product

• 19832-78-1 1-(4-methylphenyl)prop-2-en-1-one 
• 21205-91-4 9-borabicyclo[3.3.1]nonane dimer 

Downstream Products

• 81096-37-9 2,3-dimethyl-1,4-di(p-tolyl)-1,4-butanedione 
• 81096-38-0 (2S,3R)-2,3-Dimethyl-1,4-di-p-tolyl-butane-1,4-dione 

Relevant articles and documents

Selective intermolecular oxidative cross-coupling of enolates

Selective intermolecular oxidative cross-coupling of enolates, which is a bond-forming reaction between carbanion equivalents, remains as an unsolved issue despite its potential utility for the direct synthesis of unsymmetrical 1,4-diones. The main difficulty derives from the unavoidable homo-coupling. Our strategy depends on the selective one-electron oxidation of one enolate to afford an electrophilic carbonyl α-radical species, followed by trapping with another enolate. The present study demonstrates the selective oxovanadium(V)-induced cross-coupling between boron and silyl enolates.