156451-82-0Relevant academic research and scientific papers
An oxidative rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol to 1,1′-biphenyl-carbaldehydes: A mechanistic study
Ceylan, Mustafa,Findik, Esra,Secen, Hasan
experimental part, p. 559 - 568 (2009/02/07)
Acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0]heptan-6-ol gave 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes in small amounts as well as the expected rearrangement products. A detailed study of the reaction mechanism revealed that the conversion occurs via an oxidative process through the consecutive formation of cycloheptadienes, cycloheptatrienes, and 1,1′-biphenyls. The acid-catalyzed rearrangement of 6-phenylbicyclo[3.2.0] hept-2-en-6-ols gave 1- and 2-phenylcycloheptatrienes directly, from which 1,1′-biphenyl and 1,1′-biphenyl-carbaldehydes were obtained by oxidation.
Electrophilic Additions to the Bicyclobutane System of 1-Phenyl- and 1-(4-Anisyl)tricyclo2,7>heptane: Acid-Catalyzed Reactions with Water and Methanol, Addition of Acetic Acid, and Oxymercuration
Christl, Manfred,Gerstner, Erwin,Kemmer, Ralf,Llewellyn, Gareth,Bentley, T. William
, p. 367 - 380 (2007/10/02)
1-(4-Anisyl)tricyclo2,7>heptane (37) was prepared from 1-(4-anisyl)cyclohexene, tetrabromomethane, and methyllithium in a one-pot reaction.Starting from 37 and the analogous phenyl compound 19, the oxymercuration/demercuration sequence
