72657-59-1Relevant academic research and scientific papers
Hot water-promoted cyclopropylcarbinyl rearrangement facilitates construction of homoallylic alcohols
Li, Pei-Fang,Yi, Cheng-Bo,Qu, Jin
, p. 5012 - 5021 (2015/05/05)
In refluxing 9 : 1 (v/v) H2O-1,4-dioxane and without an additional catalyst, the rearrangements of various types of cyclopropyl carbinols were attempted. It was found that the reactions generally gave homoallylic alcohols in good to very high chemical yields. Rearrangements of bicyclic or tricyclic cyclopropyl carbinols readily gave the desired ring-expanded cyclic homoallylic alcohols which are difficult to synthesize by other means.
Electrophilic Additions to the Bicyclobutane System of 1-Phenyl- and 1-(4-Anisyl)tricyclo2,7>heptane: Acid-Catalyzed Reactions with Water and Methanol, Addition of Acetic Acid, and Oxymercuration
Christl, Manfred,Gerstner, Erwin,Kemmer, Ralf,Llewellyn, Gareth,Bentley, T. William
, p. 367 - 380 (2007/10/02)
1-(4-Anisyl)tricyclo2,7>heptane (37) was prepared from 1-(4-anisyl)cyclohexene, tetrabromomethane, and methyllithium in a one-pot reaction.Starting from 37 and the analogous phenyl compound 19, the oxymercuration/demercuration sequence
Preparation of 3-Cycloheptenyl and 3-Cyclooctenyl Derivatives by Solvolysis of Bicycloalkyl Esters
Hwang, Chrong-Shiong,Reusch, William
, p. 428 - 434 (2007/10/02)
Ester derivatives of 6-substituted cis-bicycloheptan-6-ol, and of 7-substituted cis-bicyclooctan-7-ol were solvolyzed to the corresponding cycloheptene and cyclooctene products.In general, acetolysis of the 3,5-dinitrobenzoates in glacial or
